Efficient Free-Radical Cyclopolymerization of Oriented Styrenic Difunctional Monomers

Date

2009

Authors

Edizer, Seda
Veronesi, Barbara
Karahan, Ozlem
Aviyente, Viktorya
Degirmenci, Isa
Galbiati, Alessandro
Pasini, Dario

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The synthesis of several difunctional monomers, derived from the introduction of two 4-styrene- substituted moieties into a covalent skeleton, is described. The more rigid ones, built around malonate moieties and more preorganized to give 3,3'-cyclophane

Description

Keywords

Keywords: Cyclophane; Degree of flexibility; Degrees of polymerizations; Difunctional; Malonate moiety; Radical cyclopolymerization; Repeating unit; Theoretical calculations; Crosslinking; Styrene; Free radical polymerization

Citation

Source

Macromolecules

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

Restricted until

2037-12-31