Model support studies toward the total synthesis of the stemona alkaloid stemocurtisine

Date

2013

Authors

Shengule, Sudhir R
Willis, Anthony
Pyne, Stephen G

Journal Title

Journal ISSN

Volume Title

Publisher

Elsevier

Abstract

Herein we report the results of a furan-based approach toward the synthesis of the Stemona alkaloid, stemocurtisine 1 via the linearly fused tricyclic intermediate 3, representing the key A,B,C-ring structural feature of the target molecule. A highly dias

Description

Keywords

Keywords: (11,11a) 11 hydroxy 5,6,9,10,11,11a hexahydrofuro [3,2 c]pyrido[1,2 a]azepin 8(4h) one; (5) 5 [azido(furan 3 yl)methyl]dihydrofuran 2(3h) one; (5) 5 [furan 3 yl(hydroxy)methyl]dihydrofuran 2(3h) one; (9,9a) 9 [(tert butyldimethylsilyl)oxy] 4,5,9,9a tetrah Azepine; Furan oxidation; Lactam; Stemona alkaloid

Citation

Source

Tetrahedron

Type

Journal article

Book Title

Entity type

Access Statement

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Restricted until

2037-12-31