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(Ethene)bis(acetylacetonato) complexes of divalent and trivalent ruthenium

Date

Authors

Bennett, Martin

Byrnes, Matthew

Willis, Anthony

Publisher

American Chemical Society

Abstract

Zinc dust reduction of tris(acetylacetonato)ruthenium(III), [Ru(acac)3], in hot aqueous THF in the presence of ethene gives cis-[Ru(acac)2(η2-C2H4)2 ] (5), isolated as an orange solid in ca. 60% yield. A single-crystal X-ray crystallographic study shows

Keywords

Keywords: Transisomers; Alumina; Carbon; Chemical bonds; Cyclic voltammetry; Electrolysis; Isomers; Nuclear magnetic resonance spectroscopy; Oxidation; Paramagnetic resonance; Positive ions; Protons; Single crystals; Thermal effects; X ray crystallography; Zinc; Ru

URI

http://hdl.handle.net/1885/87861

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

DOI

10.1021/om020815b

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