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Structural and nonlinear optical properties of aligned heterotrinuclear [Ru II -(spacer)-M II -(spacer)-Ru II ] complexes (M = Pd, Pt; spacer = 4-ethynylpyridine)

Date

Authors

Ge, Qingchun

Dalton, Gulliver

Samoc, Marek

Hor, T S Andy

Humphrey, Mark

Publisher

Wiley-VCH Verlag GMBH

Abstract

Lewis addition between the metalloligand [RuCpACHTUNGTRENUNG(C≡Cpy-4) ACHTUNGTRENUNG(dppf)] (1) (dppf=(C5H4PPh2) 2Fe) and MCl2 ACHTUNGTRENUNG(CH3CN)2 gives [RuCpACHTUNGTRENUNG(C≡Cpy-4)-ACHTUNGTRENUNG(dppf)] 2ACHTUNGTRENUNG[MCl2] (M=Pd (2) and Pt (3)),

Keywords

Keywords: Centrosymmetric; Electrochemical studies; Heterometallic; Heterometallic complexes; Metal adducts; Metal-organic; Non-linear optical properties; Nonlinear optical response; Organometallic complex; Square-planar metals; Electrochemistry; Metals; Nonlinear Electrochemistry; Heterometallic; Metal-organic; Nonlinear optics

URI

http://hdl.handle.net/1885/56727

Collections

ANU Research Publications

Source

Chemistry - An Asian Journal

Type

Journal article

DOI

10.1002/asia.200900065

Restricted until

2037-12-31

Downloads

File

Description

01_Ge_Structural_and_nonlinear_2009.pdf (407.8 KB)