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2,7-Fluorenediyl-Bridged Complexes Containing Electroactive "fe(η⁵-C₅Me₅)(k²-dppe)C=C-" End Groups: Molecular Wires and Remarkable Nonlinear Electrochromes

Malvolti, Floriane; Rouxel, Cedric; Triadon, Amedee; Grelaud, Guillaume; Richy, Nicolas; Mongin, Olivier; Blanchard-Desce, Mireille; Toupet, Loic; Abdul Razak, Fazira; Stranger, Robert; Samoc, Marek; Yang, Xinwei; Wang, Genmiao; Barlow, Adam; Cifuentes, Marie; Paul, Frederic; Humphrey, Mark


The 2,7-fluorenyl-bridged Fe(η5-C5Me5)(κ2-dppe)[C≡C(2,7-C13H6Bu2)C≡C]Fe(η5-C5Me5)(κ2-dppe) (1a), its extended analogue Fe(η5-C5Me5)(κ2-dppe)[C≡C(1,4-C6H4)C≡C(2,7-C13H6Bu2)C≡C(1,4-C6H4)C≡C](η5-C5Me5)(κ2-dppe)Fe (1b), and the corresponding mononuclear complexes Fe(η5-C5Me5)(κ2-dppe)[C≡C(2-C13H7Bu2)] (2a) and Fe(η5-C5Me5)(κ2-dppe)[C≡C(1,4-C6H4)C≡C(2-C13H7Bu2)] (2b), which model half of these molecules, have been synthesized and characterized in their various redox states. The molecular wire...[Show more]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
Source: Organometallics
DOI: 10.1021/acs.organomet.5b00769
Access Rights: Open Access


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