Diastereoselective Synthesis of the A-B-C Tricyclic Ring Structure of Stemocurtisine
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Dau, Xuan Duc; Willis, Anthony; Pyne, Stephen G
Description
The diastereoselective synthesis of the A-B-C tricyclic ring structure of the Stemona alkaloid stemocurtisine is described. This tricyclic precursor to the natural product was obtained in 19 steps from a known vinyl iodide. Attempts to prepare the C-3a-C-11 ether moiety of this alkaloid through a photochemically induced oxidative cyclization method were unsuccessful because of the cleavage of the A-ring.
dc.contributor.author | Dau, Xuan Duc | |
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dc.contributor.author | Willis, Anthony | |
dc.contributor.author | Pyne, Stephen G | |
dc.date.accessioned | 2016-02-24T22:41:30Z | |
dc.identifier.issn | 1434-193X | |
dc.identifier.uri | http://hdl.handle.net/1885/98711 | |
dc.description.abstract | The diastereoselective synthesis of the A-B-C tricyclic ring structure of the Stemona alkaloid stemocurtisine is described. This tricyclic precursor to the natural product was obtained in 19 steps from a known vinyl iodide. Attempts to prepare the C-3a-C-11 ether moiety of this alkaloid through a photochemically induced oxidative cyclization method were unsuccessful because of the cleavage of the A-ring. | |
dc.publisher | Wiley-VCH Verlag GMBH | |
dc.source | European Journal of Organic Chemistry | |
dc.title | Diastereoselective Synthesis of the A-B-C Tricyclic Ring Structure of Stemocurtisine | |
dc.type | Journal article | |
local.description.notes | Imported from ARIES | |
local.identifier.citationvolume | 2015 | |
dc.date.issued | 2015 | |
local.identifier.absfor | 030600 - PHYSICAL CHEMISTRY (INCL. STRUCTURAL) | |
local.identifier.absfor | 039900 - OTHER CHEMICAL SCIENCES | |
local.identifier.ariespublication | U3488905xPUB6849 | |
local.type.status | Published Version | |
local.contributor.affiliation | Dau, Xuan Duc, University of Wollongong | |
local.contributor.affiliation | Willis, Anthony, College of Physical and Mathematical Sciences, ANU | |
local.contributor.affiliation | Pyne, Stephen G, University of Wollongong | |
local.description.embargo | 2037-12-31 | |
local.bibliographicCitation.issue | 35 | |
local.bibliographicCitation.startpage | 7682 | |
local.bibliographicCitation.lastpage | 7694 | |
local.identifier.doi | 10.1002/ejoc.201501080 | |
dc.date.updated | 2016-02-24T10:12:21Z | |
local.identifier.scopusID | 2-s2.0-84948154868 | |
Collections | ANU Research Publications |
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