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Mechanistic Perspectives on Stereocontrol in Lewis Acid-Mediated Radical Polymerization: Lessons from Small-Molecule Synthesis

Noble, Ben; Coote, Michelle


The regulation of stereochemistry in radical polymerization has thus far proved enormously challenging, being the subject of more than 50. years of intense and innovative research. The relatively recent development of living radical polymerization has revitalized interest in stereocontrol, as the lack of tacticity control is now the greatest obstacle to the synthesis of precisely controlled macromolecules by highly versatile and efficient radical-based processes. Lewis acids (LAs) have been...[Show more]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
Source: Advances in Physical Organic Chemistry
DOI: 10.1016/bs.apoc.2015.07.002


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