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Cubic nonlinear optical properties of new zinc tetraphenyl porphyrins peripherally functionalized with electron-rich Ru(II) alkynyl substituents

Drouet, Samuel; Merhi, Areej; Yao, Dandan; Cifuentes, Marie; Wielgus, Malgorzata; Olesiak-Banska, Joanna; Matczyszyn, Katarzyna; Samoc, Marek; Paul, Frederic; Paul-Roth, Christine; Humphrey, Mark


We report the synthesis and characterization of new organometallic assemblies consisting of a central Zn(II) tetraphenylporphyrin (ZnTPP) core surrounded by four Ru(II) alkynyl complexes (trans-Ru(dppe)2R) appended at the para phenyl positions and acting as peripheral donor groups. The synthesis of the tetra-chlorido derivative 2 (R=Cl) is reported first, followed by that of three extended homologues (3-X) obtained from this building block by substitution of the chlorido ligands by...[Show more]

CollectionsANU Research Publications
Date published: 2012
Type: Journal article
Source: Tetrahedron
DOI: 10.1016/j.tet.2012.09.108


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