Cubic nonlinear optical properties of new zinc tetraphenyl porphyrins peripherally functionalized with electron-rich Ru(II) alkynyl substituents
We report the synthesis and characterization of new organometallic assemblies consisting of a central Zn(II) tetraphenylporphyrin (ZnTPP) core surrounded by four Ru(II) alkynyl complexes (trans-Ru(dppe)2R) appended at the para phenyl positions and acting as peripheral donor groups. The synthesis of the tetra-chlorido derivative 2 (R=Cl) is reported first, followed by that of three extended homologues (3-X) obtained from this building block by substitution of the chlorido ligands by...[Show more]
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