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Consequences of shifted ion adsorption equilibria due to nonelectrostatic interaction potentials in electrical double layers

Deniz, Vivianne; Fogden, Andrew


Consistent incorporation of nonelectrostatic interactions in the chemical potential for electrical double layers at interfaces interacting across electrolytes under the constant potential or charge regulation boundary conditions has recently been presented for the case of ionic dispersion potentials. This gives rise to shifted adsorption equilibria, and thereby a shift in the predicted surface electrostatic potential. It also results in an additional component previously unaccounted for in the...[Show more]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
Source: Colloids and Surfaces A: Physicochemical and Engineering Aspects
DOI: 10.1016/j.colsurfa.2015.01.013


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