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Generation of nickel(0)-aryne and nickel(II)-biphenyldiyl complexes via in situ dehydrohalogenation of arenes. Molecular structures of [Ni(2,2-C 6 H 4 C 6 H 4 )(dcpe)] and C 2 -hexabenzotriphenylene.

Bennett, Martin; Kopp, Mikchael; Wenger, Eric; Willis, Anthony

Description

Reactions of the aromatic halides chlorobenzene, 9-bromophenanthrene and chloro-p-xylene with lithium 2,2,6,6-tetramethylpiperidide (LiTMP) in the presence of [Ni(η2-C2H4)(dcpe)] (1) generated the corresponding η2-aryne complexes [Ni(η2-aryne)(dcpe)] [

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
URI: http://hdl.handle.net/1885/94247
Source: Journal of Organometallic Chemistry
DOI: 10.1016/S0022-328X(02)01667-4

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