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Oxidation State Dependence of the Geometry, Electronic Structure, and Magnetic Coupling in Mixed Oxo- and Carboxylato-Bridged Manganese Dimers

Delfs, Christopher; Stranger, Robert


Approximate density functional theory has been used to investigate changes in the geometry and electronic structure of the mixed oxo- and carboxylato-bridged dimers [Mn2(μ-O)2(O2CH) (NH3)6]n+ and [Mn2(μ-O)(O2CH)2 (NH3)6]n+ in the MnIVMnIV, MnIIIMnIV, an

CollectionsANU Research Publications
Date published: 2001
Type: Journal article
Source: Inorganic Chemistry
DOI: 10.1021/ic0008767


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