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Mixed-metal cluster chemistry. Part 14: reaction of [Cp2W2Ir2(CO)10] with trimethylphosphite; X-ray crystal structures of [Cp2W2Ir2(m-CO)3(CO)5{P(OMe)3}2] and two modifications of [CpWIr3(m-CO)3(CO)7{P(OMe)3}]

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Waterman, Susan; Hockless, David; Humphrey, Mark

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Reactions of [Cp2W2Ir2(CO)10] with stoichiometric amounts of trimethylphosphite afford the substitution products [Cp2W2Ir2(μ-CO)3(CO) 7-n{P(OMe)3}n] [n=1 (2) or 2 (3)]. A structural study of 3 reveals that the three edges of a WIr2 face of the tetrahedra

dc.contributor.authorWaterman, Susan
dc.contributor.authorHockless, David
dc.contributor.authorHumphrey, Mark
dc.date.accessioned2015-12-13T23:35:17Z
dc.identifier.issn0022-328X
dc.identifier.urihttp://hdl.handle.net/1885/93848
dc.description.abstractReactions of [Cp2W2Ir2(CO)10] with stoichiometric amounts of trimethylphosphite afford the substitution products [Cp2W2Ir2(μ-CO)3(CO) 7-n{P(OMe)3}n] [n=1 (2) or 2 (3)]. A structural study of 3 reveals that the three edges of a WIr2 face of the tetrahedra
dc.publisherElsevier
dc.sourceJournal of Organometallic Chemistry
dc.subjectKeywords: Carbonyl; Cluster; Iridium; Phosphite; Tungsten
dc.titleMixed-metal cluster chemistry. Part 14: reaction of [Cp2W2Ir2(CO)10] with trimethylphosphite; X-ray crystal structures of [Cp2W2Ir2(m-CO)3(CO)5{P(OMe)3}2] and two modifications of [CpWIr3(m-CO)3(CO)7{P(OMe)3}]
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.citationvolume582
dc.date.issued1999
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub25269
local.type.statusPublished Version
local.contributor.affiliationWaterman, Susan, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHumphrey, Mark, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHockless, David, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.startpage310?318
dc.date.updated2015-12-12T09:39:23Z
local.identifier.scopusID2-s2.0-0003295556
CollectionsANU Research Publications

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