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Electron paramagnetic resonance and electron spin echo study of supported and unsupported vanadium oxides

Luca, Vittorio; MacLachlan, Dugald; Bramley, Richard


Electron paramagnetic resonance (EPR) and electron spin echo envelope modulation (ESEEM) spectroscopies have been used to characterize paramagnetic centers in crystalline and gel forms of vanadium pentoxide as well as vanadia supported on silica, titania, and magnesia. A number of different paramagnetic centers are observed in the bulk and supported vanadia phases that are characterized by their spin Hamiltonian parameters. ESEEM data for all the bulk vanadium oxide samples show intense...[Show more]

CollectionsANU Research Publications
Date published: 1999
Type: Journal article
Source: Physical Chemistry Chemical Physics
DOI: 10.1039/a900119k


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