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Structures of Bi14WO24 and Bi14MoO24 from neutron powder diffraction data

Ling, Christopher; Withers, Raymond; Thompson, John; Schmid, Siegbert


The (isomorphous) structures of Bi14WO24, tetradecabismuth tungsten tetracosaoxide, and Bi14MoO24, tetradecabismuth molybdenum tetracosaoxide, have been solved and refined using neutron powder diffraction data in the space group I4/m. The metal-atom array is fully ordered in terms of composition, and in terms of atomic positions deviates only slightly from a fluorite-type δ-Bi2O3-related parent structure. Three independent O-atom sites (accounting for 70 out of 78 O atoms in the unit cell) are...[Show more]

CollectionsANU Research Publications
Date published: 1999
Type: Journal article
Source: Acta Crystallographica Section B: Structural Science


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