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Sterically induced transmutations in cobalt amine chemistry

Skelton, Brian; Qin, Chang; Ralph, Stephen; White, Allan; Willis, Anthony

Description

Steric forces within a hexaaza bicyclic cobalt cage system cause chromophore expansions which bring about extraordinary transformations in the CoN6 chemistry, leading to Co(III/II)N6 redox potentials close to +0.8 V (vs. SHE) and Co(II) hexaamine complexes that are air and substitution stable.

dc.contributor.authorSkelton, Brian
dc.contributor.authorQin, Chang
dc.contributor.authorRalph, Stephen
dc.contributor.authorWhite, Allan
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-13T23:35:10Z
dc.date.available2015-12-13T23:35:10Z
dc.identifier.issn1359-7345
dc.identifier.urihttp://hdl.handle.net/1885/93783
dc.description.abstractSteric forces within a hexaaza bicyclic cobalt cage system cause chromophore expansions which bring about extraordinary transformations in the CoN6 chemistry, leading to Co(III/II)N6 redox potentials close to +0.8 V (vs. SHE) and Co(II) hexaamine complexes that are air and substitution stable.
dc.publisherRoyal Society of Chemistry
dc.sourceChemical Communications
dc.subjectKeywords: amine; cobalt derivative; article; chemical structure; nuclear magnetic resonance spectroscopy; oxidation reduction potential; potentiometry; stereochemistry
dc.titleSterically induced transmutations in cobalt amine chemistry
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
dc.date.issued1999
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub25195
local.type.statusPublished Version
local.contributor.affiliationSkelton, Brian, University of Western Australia
local.contributor.affiliationQin, Chang, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationRalph, Stephen, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWhite, Allan, University of Western Australia
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.bibliographicCitation.startpage2351
local.bibliographicCitation.lastpage2352
dc.date.updated2015-12-12T09:38:53Z
local.identifier.scopusID2-s2.0-0033534104
CollectionsANU Research Publications

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