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Sterically induced transmutations in cobalt amine chemistry

Skelton, Brian; Qin, Chang; Ralph, Stephen; White, Allan; Willis, Anthony


Steric forces within a hexaaza bicyclic cobalt cage system cause chromophore expansions which bring about extraordinary transformations in the CoN6 chemistry, leading to Co(III/II)N6 redox potentials close to +0.8 V (vs. SHE) and Co(II) hexaamine complexes that are air and substitution stable.

CollectionsANU Research Publications
Date published: 1999
Type: Journal article
Source: Chemical Communications


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