Adsorption of carbon tetrachloride by 3.4 nm pore diameter siliceous MCM-41: isotherms and neutron diffraction
Branton, Peter; Reynolds, Philip; Studer, Andrew J; Sing, Kenneth; White, John
Adsorption isotherms of carbon tetrachloride at temperatures between 273 and 323 K have been determined on the pure silica form of MCM-41 of pore diameter ca. 3.4 nm. All isotherms were of Type V, the isotherms at 273, 288 and 303 K showing hysteresis loops, whereas the isotherm at 323 K was completely reversible. Despite the questionable validity of the Kelvin equation when applied to narrow mesopores, changes in the relative pressure positions of capillary condensation and evaporation as a...[Show more]
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