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Adsorption of carbon tetrachloride by 3.4 nm pore diameter siliceous MCM-41: isotherms and neutron diffraction

Branton, Peter; Reynolds, Philip; Studer, Andrew J; Sing, Kenneth; White, John

Description

Adsorption isotherms of carbon tetrachloride at temperatures between 273 and 323 K have been determined on the pure silica form of MCM-41 of pore diameter ca. 3.4 nm. All isotherms were of Type V, the isotherms at 273, 288 and 303 K showing hysteresis loops, whereas the isotherm at 323 K was completely reversible. Despite the questionable validity of the Kelvin equation when applied to narrow mesopores, changes in the relative pressure positions of capillary condensation and evaporation as a...[Show more]

CollectionsANU Research Publications
Date published: 1999
Type: Journal article
URI: http://hdl.handle.net/1885/93759
Source: Adsorption

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