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Insertions of unsymmetric alkynes into the metal-carbon bonds of nickelacycles: What determines the regiochemistry?

Bennett, Martin; Macgregor, Stuart A; Wenger, Eric

Description

Although the insertion of alkynes into transition-metal - carbon bonds plays an important role in synthesis, the regioselectivities observed with unsymmetric alkynes have usually been interpreted on the basis of steric effects. In this perspective paper,

CollectionsANU Research Publications
Date published: 2001
Type: Journal article
URI: http://hdl.handle.net/1885/93308
Source: Helvetica Chimica Acta
DOI: 10.1002/1522-2675(20011017)84:10<3084::AID-HLCA3084>3.0.CO;2-H

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