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Metallathiirenes. 3. Thiocarbamoyl and alkoxythiocarbonyl complexes of molybdenum(II) and tungsten(II)

Anderson, Stephen; Cook, Darren J; Hill, Anthony

Description

Synthetic routes to thiocarbamoyl (thiocarboxamide) complexes of divalent molybdenum and tungsten are reported: The reaction of fac-[Mo(CO)3(NCMe)3] with N,N-dimethyl thiocarbamoyl chloride (Me2NC(=S)Cl) at low temperature provides a thermally labile intermediate (1) presumed on the basis of subsequent transformations to be [Mo(η2-SCNMe2)-Cl(CO)3(NCMe)]. Reactions of 1 with K[HB(pz)3] (pz = pyrazol-1-yl), NaC5H5, bipy, or tmeda provide the complexes [Mo(η2-SCNMe2)(CO)2{HB(pz)3}] (2),...[Show more]

CollectionsANU Research Publications
Date published: 2001
Type: Journal article
URI: http://hdl.handle.net/1885/93252
Source: Organometallics
DOI: 10.1021/om991019h

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