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Oxidation chemistry of metal-bonded C4 chains: A combined chemical, spectroelectrochemical, and computational study

Bruce, Michael; Low, Paul J; Costuas, Karine; Halet, J-F; Best, Stephen Peter; Heath, Graham

Description

The known complex {Cp(PPh3)2Ru}2(μ-C≡CC≡C) (3-Ph) and its PMe3- substitution product {Cp(PPh3)(PMe3)Ru}2(μ-C≡CC≡C) (3-Me) have been shown by cyclic voltammetry to undergo a series of four stepwise one-electron oxidation processes. Successive oxi

CollectionsANU Research Publications
Date published: 2000
Type: Journal article
URI: http://hdl.handle.net/1885/93226
Source: Journal of the American Chemical Society
DOI: 10.1021/ja992002t

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