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Organometallic complexes for nonlinear optics Part 23. Quadratic and cubic hyperpolarizabilities of acetylide and vinylidene complexes derived from protected and free formylphenylacetylenes

Hurst, Stephanie; Lucas, Nigel; Cifuentes, Marie; Samoc, Marek; Luther-Davies, Barry; Asselberghs, Inge; Van Boxel, Roel; Persoons, Andre Pierre; Humphrey, Mark


The acetylenes 4-HCCC6H4R [R=CH{OC(O)Me}2 (1), CHO(CH2)3O (2)], ruthenium complexes [Ru(4-CCC6H4R)(PPh3)2(η-C 5H5)] [R=CH{OC(O)Me}2 (3), CHO (4)], [Ru(n-C=CHC6H4R)Cl(dppm)2]PF6 [n=4, R=CHO(CH2)3O (7); R=CHO, n=3 (11), 2 (15)], and [Ru(n-CCC6H4R)Cl(dppm)2

CollectionsANU Research Publications
Date published: 2001
Type: Journal article
Source: Journal of Organometallic Chemistry
DOI: 10.1016/S0022-328X(01)01077-4


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