Factors controlling the addition of carbon-centered radicals to alkenes-an experimental and theoretical perspective
The successful exploitation of syntheses involving the generation of new carbon - carbon bonds by radical reactions rests on some prior knowledge of the rate constants for the addition of carbon-centered radicals to alkenes and other unsaturated molecules, and of the factors controlling them. Two former classical reviews in Angewandte Chemie by Tedder (1982) and by Giese (1983) provided mechanistic insight and led to various qualitative rules on the complex interplay of enthalpic, polar, and...[Show more]
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