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The strain-driven pyrochlore to defect fluorite phase transition in rare earth sesquioxide stabilized cubic zirconias

Tabira, Y.; Withers, Raymond; Barry, J C; Elcoro, Luis


The relationship between the ordering characteristic of the pyrochlore structure type and that characteristic of the "defect fluorite" structure type (immediately on either side of two phase regions separating the two structure types) in a range of rare eath sesquioxide stabilized cubic zirconias is investigated via electron diffraction and imaging. Systematic structural change as a function of composition and relative size of the constituent metal ions is highlighted and a multi-q to single-q...[Show more]

CollectionsANU Research Publications
Date published: 2001
Type: Journal article
Source: Journal of Solid State Chemistry
DOI: 10.1006/jssc.2001.9139


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