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Mixed-metal cluster chemistry Part 20. Syntheses, crystal structures and electrochemical studies of W 2 Ir 2 (u-L)(CO) 8 (η 5 -C 5 H 4 Me) 2 (L = dppe, dppf)

Blitz, Jonathan; Lucas, Nigel; Humphrey, Mark

Description

The 60-electron tetrahedral clusters W2Ir2(μ-L)(CO)8(η5-C5H4Me)2 [L = dppe (2), dppf (3)] have been prepared from reaction between W2Ir2 (CO)10(η5-C5H4Me)2 (1) and the corresponding diphosphine in 52 amd 66% yields, respectively. A structiral study of

CollectionsANU Research Publications
Date published: 2002
Type: Journal article
URI: http://hdl.handle.net/1885/92391
Source: Journal of Organometallic Chemistry
DOI: 10.1016/S0022-328X(02)01201-9

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