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Tricarbonyl(dihydroazepinyl)chromium Complexes and Methylene-pyrrolidines from (2-dimethylaminoethenyl)carbenechromium Complexes

Schirmer, Heiko; Labahn, Thomas; Flynn, Bernard; Wu, Yao-Ting; de Meijere, Armin

Description

The (3-amino-1-ethoxyalkenylidene)pentacarbonylchromium complexes 1 and 8 react with bulkily substituted terminal alkynes 2 and 9 in tetrahydrofuran to give η5-tricarbonyl(dihydroazepinyl)chromium complexes 3 and 12a which can be isolated in low yields.

CollectionsANU Research Publications
Date published: 1999
Type: Journal article
URI: http://hdl.handle.net/1885/92083
Source: Synlett

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