Redox-Induced Formation and Cleavage of O-O Bonds in a Peroxo-Bridged Manganese Dimer: a Density Functional Study
The structural and electronic consequences of reduction and oxidation of a peroxo-bridged Mn2IV/IV dimer, Mn2(μ-O)2(μ-O2)(NH3) 62+, are examined using approximate density functional theory. In both cases, the initial electron-transfer step is localized
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