Synthesis and properties of cobalt(III) complexes of tripodal ligands containing amide functional groups
Angus, Patricia; Elliott, Anthony; Sargeson, Alan; Willis, Anthony
Description
Two new, trigonally symmetrical, triamide tripodal ligands and their complexes with the cobalt(III) ion, [1,1,1-tris-(4-amino-1-oxo-2-azabutyl)ethanato]cobalt(III)trihydrate 1 and [1,1,1-tris(4-amino-4-methyl-3-oxo-2-azapentyl)-ethanato]cobalt(III)-water- ethanol (1/8/0.5) 2 have been prepared. The hexadentate structures of the neutral, trigonal, triamido complexes have been established by an X-ray study of 1 and 13C NMR spectrometry of both molecules. The chemical, spectroscopic and...[Show more]
dc.contributor.author | Angus, Patricia | |
---|---|---|
dc.contributor.author | Elliott, Anthony | |
dc.contributor.author | Sargeson, Alan | |
dc.contributor.author | Willis, Anthony | |
dc.date.accessioned | 2015-12-13T23:23:10Z | |
dc.date.available | 2015-12-13T23:23:10Z | |
dc.identifier.issn | 1477-9226 | |
dc.identifier.uri | http://hdl.handle.net/1885/91791 | |
dc.description.abstract | Two new, trigonally symmetrical, triamide tripodal ligands and their complexes with the cobalt(III) ion, [1,1,1-tris-(4-amino-1-oxo-2-azabutyl)ethanato]cobalt(III)trihydrate 1 and [1,1,1-tris(4-amino-4-methyl-3-oxo-2-azapentyl)-ethanato]cobalt(III)-water- ethanol (1/8/0.5) 2 have been prepared. The hexadentate structures of the neutral, trigonal, triamido complexes have been established by an X-ray study of 1 and 13C NMR spectrometry of both molecules. The chemical, spectroscopic and electrochemical properties of the complexes have been investigated as well as those of the monoamido tripodal complex [1,9-diamino-5-(4-amino-2-azabutyl)-5-ethoxycarbonyl-4-oxo-3,7-diazanonanato] cobalt(III) chloride. | |
dc.publisher | Royal Society of Chemistry | |
dc.source | Dalton Transactions | |
dc.title | Synthesis and properties of cobalt(III) complexes of tripodal ligands containing amide functional groups | |
dc.type | Journal article | |
local.description.notes | Imported from ARIES | |
local.description.refereed | Yes | |
dc.date.issued | 1999 | |
local.identifier.absfor | 039904 - Organometallic Chemistry | |
local.identifier.ariespublication | MigratedxPub22658 | |
local.type.status | Published Version | |
local.contributor.affiliation | Angus, Patricia, College of Physical and Mathematical Sciences, ANU | |
local.contributor.affiliation | Elliott, Anthony, College of Physical and Mathematical Sciences, ANU | |
local.contributor.affiliation | Sargeson, Alan, College of Physical and Mathematical Sciences, ANU | |
local.contributor.affiliation | Willis, Anthony, College of Physical and Mathematical Sciences, ANU | |
local.bibliographicCitation.startpage | 1131 | |
local.bibliographicCitation.lastpage | 1136 | |
dc.date.updated | 2015-12-12T09:14:20Z | |
local.identifier.scopusID | 2-s2.0-33748513014 | |
Collections | ANU Research Publications |
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