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Metallocyclodextrin catalysts for hydrolysis of phosphate triesters

Barr, Lorna; Easton, Christopher; Lee, Kitty; Lincoln, Stephen F; Simpson, Jamie S


The copper complexes of 6A-(2-aminoethylamino)- and 6A-(3-aminopropylamino)-6A-deoxy-β-cyclodextrin catalyse the hydrolysis of 4-tert-butyl-2-nitrophenyl dimethyl phosphate, with kinc=3.1×10-2 and 2.3×10-2 s-1, and Kd=4.3×10-4 and 1.2×10-3 M, respect

CollectionsANU Research Publications
Date published: 2002
Type: Journal article
Source: Tetrahedron Letters
DOI: 10.1016/S0040-4039(02)01757-4


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