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Enantioselective synthesis of a conformationally rigid, sterically encumbered, 2-arsino-7-phosphanorbornene.

Gugger, Paul; Willis, Anthony; Wild, Stanley (Bruce); Heath, Graham; Webster, Richard; Nelson, John H


Convenient access to the enantionerically pure, conformationally rigid, ligand has been established by intramolecular [4 + 2]-Diels-Alder cycloaddition between dicyclohexylvinylarsine and 3,4-dimethyl-1-phenylphosphole using chiral organopalladium(II) complexes containing orthometallated (S)-1-α-(dimethylamino)ethylnaphthalene or (R)-2-α-(dimethylamino)ethylnaphthalene as the reaction templates. The ligand was displaced from the palladium complex with cyanide and reacted with [η6-arene)RuCl2]2...[Show more]

CollectionsANU Research Publications
Date published: 2002
Type: Journal article
Source: Journal of Organometallic Chemistry
DOI: 10.1016/S0022-328X(01)01209-8


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