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New macrocyclic ligands. XIV. Synthesis and X-ray structures of potentially pentadentate ligands incorporating non-symmetrically arranged N 4 S-, N 3 OS-, N 2 O 2 S- and N 2 S 2 O-heteroatoms.

Baldwin, Darren; Bowden, Bruce; Duckworth, Paul; Lindoy, Leonard; McCool, Brian; Meehan, George; Vasilescu, Ioana; Wild, Stanley (Bruce)


The synthesis and characterization of new mixed-donor macrocyclic ligands incorporating nitrogen, sulfur and/or oxygen heteroatoms are described. The new 17- or 18-membered macrocyclic rings contain unsymmetrical arrangements of their heteroatoms in contrast to related, previously reported rings in which the donor sets are arranged symmetrically. The X-ray structures of the 17-membered rings incorporating N4O- and N4S-donor sets are presented.

CollectionsANU Research Publications
Date published: 2002
Type: Journal article
Source: Australian Journal of Chemistry
DOI: 10.1071/CH02121


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