New macrocyclic ligands. XIV. Synthesis and X-ray structures of potentially pentadentate ligands incorporating non-symmetrically arranged N 4 S-, N 3 OS-, N 2 O 2 S- and N 2 S 2 O-heteroatoms.
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Baldwin, Darren; Bowden, Bruce; Duckworth, Paul; Lindoy, Leonard; McCool, Brian; Meehan, George; Vasilescu, Ioana; Wild, Stanley (Bruce)
Description
The synthesis and characterization of new mixed-donor macrocyclic ligands incorporating nitrogen, sulfur and/or oxygen heteroatoms are described. The new 17- or 18-membered macrocyclic rings contain unsymmetrical arrangements of their heteroatoms in contrast to related, previously reported rings in which the donor sets are arranged symmetrically. The X-ray structures of the 17-membered rings incorporating N4O- and N4S-donor sets are presented.
Collections | ANU Research Publications |
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Date published: | 2002 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/91685 |
Source: | Australian Journal of Chemistry |
DOI: | 10.1071/CH02121 |
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