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Mixed-metal cluster chemistry. 19. Crystallographic, spectroscopic, electrochemical, spectroelectrochemical, and theoretical studies of systematically varied tetrahedral group 6-iridium clusters

Lucas, Nigel; Blitz, Jonathan; Petrie, Simon; Stranger, Robert; Heath, Graham; Otieno-Alego, Vincent; Humphrey, Mark


A systematically varied series of tetrahedral clusters involving ligand and core metal variation has been examined using crystallography, Raman spectroscopy, cyclic voltammetry, UV - vis - NIR and IR spectroelectrochemistry, and approximate density functional theory, to assess cluster rearrangement to accommodate steric crowding, the utility of metal-metal stretching vibrations in mixed-metal cluster characterization, and the possibility of tuning cluster electronic structure by systematic...[Show more]

CollectionsANU Research Publications
Date published: 2002
Type: Journal article
Source: Journal of the American Chemical Society
DOI: 10.1021/ja0173829


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