Mixed-metal cluster chemistry. 19. Crystallographic, spectroscopic, electrochemical, spectroelectrochemical, and theoretical studies of systematically varied tetrahedral group 6-iridium clusters
A systematically varied series of tetrahedral clusters involving ligand and core metal variation has been examined using crystallography, Raman spectroscopy, cyclic voltammetry, UV - vis - NIR and IR spectroelectrochemistry, and approximate density functional theory, to assess cluster rearrangement to accommodate steric crowding, the utility of metal-metal stretching vibrations in mixed-metal cluster characterization, and the possibility of tuning cluster electronic structure by systematic...[Show more]
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|01_Lucas_Mixed-metal_cluster_chemistry._2002.pdf||243.23 kB||Adobe PDF||Request a copy|
|02_Lucas_Mixed-metal_cluster_chemistry._2002.pdf||238.5 kB||Adobe PDF||Request a copy|
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