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Synthesis of chiral multidentate tertiary arsines with As4 or As6 donor atoms

Doyle, Roy; Habermehl, Nicolle; Salem, Geoffrey; Willis, Anthony


Reaction of l,l,l-tris(chloromethyl)ethane with ca. three equivalents of sodium or lithium (2-dimethylarsinophenyl)methylarsenide in thf gave several products including the tetra(tertiary arsine) (R*,RAi*)-, (RAs*,SAi*,r*)and (RAs*,5 As*,5*)-l-(chloromethyl)-l,l-bis{[(2- dimethylarsinophenyl)methylarsino]methyl}ethane and the hexa(tertiary arsine) (As*,R As*,ßAs*)-l,l,l-tris{[(2-dimethylarsinophenyl) methylarsino]methyl}ethane. The latter is the first example of a chiral hexa(tertiary arsine)....[Show more]

CollectionsANU Research Publications
Date published: 2000
Type: Journal article
Source: Dalton Transactions
DOI: 10.1039/b003981k


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