Trends in back-bonding in the series trans-[M(C�CR)Cl(PH3)4] (M = Fe, Ru, Os; R = H, Ph, C6H4NO2-4)
Delfs, Christopher; Stranger, Robert; McDonagh, Andrew; Humphrey, Mark
Description
The electronic structure of the complexes trans-[M(C≡CR)Cl(PH3)4] (M = Fe, Ru, Os; R = H, Ph, C6H4NO2-4) has been investigated using approximate density functional theory in order to examine the M-C back-bonding interaction. For all three metal systems,
Collections | ANU Research Publications |
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Date published: | 2000 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/91294 |
Source: | Journal of Organometallic Chemistry |
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