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Trends in back-bonding in the series trans-[M(C�CR)Cl(PH3)4] (M = Fe, Ru, Os; R = H, Ph, C6H4NO2-4)

Delfs, Christopher; Stranger, Robert; Humphrey, Mark; McDonagh, Andrew


The electronic structure of the complexes trans-[M(C≡CR)Cl(PH3)4] (M = Fe, Ru, Os; R = H, Ph, C6H4NO2-4) has been investigated using approximate density functional theory in order to examine the M-C back-bonding interaction. For all three metal systems,

CollectionsANU Research Publications
Date published: 2000
Type: Journal article
Source: Journal of Organometallic Chemistry


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