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Magnetic Exchange in [Mn2(m-O)3(tmtacn)2]2+: Metal-Metal Bonding or Superexchange?

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Delfs, Christopher; Stranger, Robert

Description

A computational study of the tris-μ-oxo-bridged manganese dimer [Mn2(μ-O)3(NH3)6]2+ as a model for [Mn2(μ-O)3(tmtacn)2]2+ (tmtacn = N',N'',N'''-trimethyl-1,4,7-triazacyclononane) has been undertaken to investigate the magnetic coupling in this complex.

CollectionsANU Research Publications
Date published: 2000
Type: Journal article
URI: http://hdl.handle.net/1885/91293
Source: Inorganic Chemistry
DOI: 10.1021/ic990790h

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