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Organometallic complexes for nonlinear optics Part 20. Syntheses and molecular quadratic hyperpolarizabilities of alkynyl complexes derived from (E)-4,4-HCCC6H4N=NC6H4NO2

McDonagh, Andrew; Lucas, Nigel; Cifuentes, Marie; Humphrey, Mark; Houbrechts, Stephan; Persoons, Andre Pierre

Description

The syntheses of the alkyne (E)-4,4′-HCCC6H4N=NC6H4NO 2 (1) and alkynyl complexes LnM{(E)-4,4′-CCC6H4N=NC6H 4NO2} [LnM=trans-[RuCl(dppm)2] (2), Ru(PPh3)2(η-C5H5) (3), Au(PPh3) (4)] are reported. A structural study of 2 reveals E stereochemistry about

CollectionsANU Research Publications
Date published: 2000
Type: Journal article
URI: http://hdl.handle.net/1885/91193
Source: Journal of Organometallic Chemistry

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