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Probing the Mn oxidation states in the OEC. Insights from spectroscopic, computational and kinetic data

Kuzek, D; Pace, Ronald

Description

Results from a variety of experimental techniques which have been used to define the oxidation levels of Mn and other components in the S states of the water oxidising complex in Photosystem II are reviewed. A self-consistent interpretation of Mn X-ray absorption near edge spectroscopy, UV-visible and near infrared spectroscopic data suggests that Mn oxidation occurs only on the S0→S1 transition, and that all four Mn centres have formal oxidation state III thereafter. Ligand oxidation occurs on...[Show more]

CollectionsANU Research Publications
Date published: 2000
Type: Journal article
URI: http://hdl.handle.net/1885/90856
Source: Biochimica et Biophysica Acta: International journal of Biochemistry and Biophysics
DOI: 10.1016/S0005-2728(00)00218-8

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