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An hermaphrodite [2]rotaxane: preparation and analysis of structure

Onagi, Hideki; Easton, Christopher; Lincoln, Stephen F


(matrix presented) The pictured rotaxane is assembled in water by capping a substituted cyclodextrin composed of the wheel and axle components. The unusual dimeric structure of the rotaxane reflects the thermodynamics of the assembly process. In N,N-dimethylformamide, the corresponding monomer is the predominant product.

CollectionsANU Research Publications
Date published: 2001
Type: Journal article
Source: Organic Letters
DOI: 10.1021/ol015607e


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