Unprecedented Regio- and Stereoselective Conversion of 1-Cyclopropyl-3-ethoxy-cyclopentadienes to 3-(E)-Alkylidene-cyclopentenes
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Flynn, Bernard; de Meijere, Armin
Description
Cyclopropylalkynes 1 were converted into cyclopropyl-substituted 3- ethoxy-5-dimethylaminocyclopentadienes 4 via initially formed (β- dimethylaminoethenyl)carbene complexes 3 and their subsequent formal [3 + 2] cycloaddition to a second alkyne of type 1
Collections | ANU Research Publications |
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Date published: | 1999 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/90671 |
Source: | Journal of Organic Chemistry |
DOI: | 10.1021/jo980938z |
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