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Unprecedented Regio- and Stereoselective Conversion of 1-Cyclopropyl-3-ethoxy-cyclopentadienes to 3-(E)-Alkylidene-cyclopentenes

Flynn, Bernard; de Meijere, Armin

Description

Cyclopropylalkynes 1 were converted into cyclopropyl-substituted 3- ethoxy-5-dimethylaminocyclopentadienes 4 via initially formed (β- dimethylaminoethenyl)carbene complexes 3 and their subsequent formal [3 + 2] cycloaddition to a second alkyne of type 1

CollectionsANU Research Publications
Date published: 1999
Type: Journal article
URI: http://hdl.handle.net/1885/90671
Source: Journal of Organic Chemistry
DOI: 10.1021/jo980938z

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