Skip navigation
Skip navigation

Vibrational analysis and ring-puckering inversion barrier of perfluorocyclopentene

Fischer, Gad; Cao, Xiaolin

Description

Perfluorocyclopentene, like cyclopentene, is expected to have a nonplanar structure with a low barrier to inversion. However, in contrast to cyclopentene, no cluster of bands that could be assigned to the ringpuckering vibration has been reported in the infrared and Raman spectra. To address this problem, ab initio molecular orbital calculations have been carried out to determine the structure and harmonic vibrational frequencies of the puckered molecule (Cs), and the molecule constrained to...[Show more]

CollectionsANU Research Publications
Date published: 1999
Type: Journal article
URI: http://hdl.handle.net/1885/90660
Source: Journal of Physical Chemistry A

Download

File Description SizeFormat Image
01_Fischer_Vibrational_analysis_and_1999.pdf59.21 kBAdobe PDF    Request a copy


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  20 July 2017/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator