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Chemoenzymatic approaches to the decahydro-as-indacene cores associated with the spinosyn class of insecticide

Banwell, Martin; Hockless, David; Jarrott, Bevyn; Kelly, Brian; Knill, A; Longmore, Robert; Simpson, Gregory Wayne


The enantiopure dienes 8 and 24, which have been prepared by chemoenzymatic methods, engage in Diels-AIder cycloaddition reactions with maleic and citraconic anhydride to give adducts (e.g. 25-27) embodying the ABC-ring system associated with spinosyns A

CollectionsANU Research Publications
Date published: 2000
Type: Journal article
Source: Journal of the Chemical Society, Perkin Transactions 1
DOI: 10.1039/b006759h


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