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Electrocyclic Ring-Opening/p-Allyl Cation Cyclization Reaction Sequences Involving gem-Dihalocyclopropanes as Substrates: Application to Syntheses of (+)-, (+)-, and (-)-g-Lycorane

Banwell, Martin; Harvey, Joanne; Hockless, David; Wu, Angela W

Description

The readily prepared gem-dibromocyclopropanes (±)-13 and (±)-19 each engage in a silver(I)-promoted electrocyclic ring-opening/π-allyl cation cyclization sequence to deliver the hexahydroindole (±)-20, which participates in a Suzuki cross-coupling rea

CollectionsANU Research Publications
Date published: 2000
Type: Journal article
URI: http://hdl.handle.net/1885/90358
Source: Journal of Organic Chemistry
DOI: 10.1021/jo991791u

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