Electrocyclic Ring-Opening/p-Allyl Cation Cyclization Reaction Sequences Involving gem-Dihalocyclopropanes as Substrates: Application to Syntheses of (+)-, (+)-, and (-)-g-Lycorane
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Banwell, Martin; Harvey, Joanne; Hockless, David; Wu, Angela W
Description
The readily prepared gem-dibromocyclopropanes (±)-13 and (±)-19 each engage in a silver(I)-promoted electrocyclic ring-opening/π-allyl cation cyclization sequence to deliver the hexahydroindole (±)-20, which participates in a Suzuki cross-coupling rea
Collections | ANU Research Publications |
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Date published: | 2000 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/90358 |
Source: | Journal of Organic Chemistry |
DOI: | 10.1021/jo991791u |
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