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Formation of (Diphenylphosphino)naphthalenes by Double Insertion of (Alkynyl)diphenylphosphines into Nickel(0)-Benzyne Complexes

Bennett, Martin; Cobley, Christopher; Rae, A David; Wenger, Eric; Willis, Anthony

Description

(Alkynyl)diphenylphosphines Ph2PC≡CR (R = H, Me, Ph, PPh2) undergo double insertion into the nickel(0)-benzyne bond of the complexes [Ni{(1,2-η)-4,5-X2C6H2}(PEt 3)2] (X = H (1a), F (1b)) to give mixtures of nickel(O) complexes containing (diphenylphosp

CollectionsANU Research Publications
Date published: 2000
Type: Journal article
URI: http://hdl.handle.net/1885/90194
Source: Organometallics

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