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Magneto-optic measurements of spectral holes in metallo-porphyrin derivatives in polymer matrices

Purchase, Robin; Sellars, Matthew; Krausz, Elmars; Manson, Neil


Magneto-optic measurements on spectral holes in the Q band of zinc phthalocyanine and zinc tetrabenzoporphyrin are reported. Detailed modelling of the changes in hole shape in the magnetic field requires the inclusion of a broad distribution of crystal-field splittings and a Ham factor of 0.52 ± 0.03. Magnetic circular dichroism (MCD) spectra are also reported for spectral holes in zinc phthalocyanine and zinc tetrabenzoporphyrin. The wavelength dependence of the hole MCD gives insight into the...[Show more]

CollectionsANU Research Publications
Date published: 2000
Type: Journal article
Source: Physical Chemistry Chemical Physics
DOI: 10.1039/b003851m


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