Magneto-optic measurements of spectral holes in metallo-porphyrin derivatives in polymer matrices
Purchase, Robin; Sellars, Matthew; Krausz, Elmars; Manson, Neil
Description
Magneto-optic measurements on spectral holes in the Q band of zinc phthalocyanine and zinc tetrabenzoporphyrin are reported. Detailed modelling of the changes in hole shape in the magnetic field requires the inclusion of a broad distribution of crystal-field splittings and a Ham factor of 0.52 ± 0.03. Magnetic circular dichroism (MCD) spectra are also reported for spectral holes in zinc phthalocyanine and zinc tetrabenzoporphyrin. The wavelength dependence of the hole MCD gives insight into the...[Show more]
Collections | ANU Research Publications |
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Date published: | 2000 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/90085 |
Source: | Physical Chemistry Chemical Physics |
DOI: | 10.1039/b003851m |
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