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Models for Free-Radical Copolymerization Propagation Kinetics

Coote, Michelle; Davis, Thomas P; Radom, Leo


The alternative models for copolymerization kinetics are critically examined using recent experimental and theoretical results - both from our own work, and from other recent studies - with the aim of identifying a suitable replacement for the terminal model as the basis of copolymerization kinetics. Based on the combined results of these studies, it is concluded that the explicit penultimate model should be adopted as the basis of free-radical copolymerization kinetics, and that the origin of...[Show more]

CollectionsANU Research Publications
Date published: 2000
Type: Conference paper
Source: Controlled/Living Radical Polymerization: Progress in ATRP, NMP, and RAFT, ACS Symposium Series, 768


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