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Structural, Spectroscopic, and Electrochemical Studies of Binuclear Manganese(II) Complexes of Bis(pentadentate) Ligands Derived from Bis(1,4,7-triazacyclononane) Macrocycles

Brudenell, Suzanne; Spiccia, Leone; Bond, I A; Fallon, G; Hockless, David; Lazarev, G; Mahon, Peter; Tiekink, Edward R


Structural, electrochemical, ESR, and H2O2 reactivity studies are reported for [Mn(dmptacn)Cl]ClO4 (1, dmptacn = 1,4-bis(2-pyridylmethyl)-1,4,7-triazacyclononane) and binuclear complexes of bis(pentadentate) ligands, generated by attaching 2-pyridylmethyl arms to each secondary nitrogen in bis(1,4,7-triazacyclononane) macrocycles and linked by ethyl (tmpdtne, [Mn2(tmpdtne)Cl2](ClO4)2·2DMF, 2), propyl (tmpdtnp, [Mn2(tmpdtnp)Cl2](ClO4)2· 3H2O, 3), butyl (tmpdtnb,...[Show more]

CollectionsANU Research Publications
Date published: 2000
Type: Journal article
Source: Inorganic Chemistry
DOI: 10.1021/ic9814470


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