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Towards Detection of a Long-lived Protonated Metal Cation: Generation of GeH2+ Using High-Energy Collisions

Jackson, Phillip; Diefenbach, Martin; Srinivas, Ragampeta; Schroder, Detlef; Schwarz, Helmut

Description

A minimal lifetime of microseconds is displayed by the dication GeH2+, which has been detected for the first time as the product of charge-stripping experiments at 8 kV involving [GeH2]+ and O2. Coupled-cluster calculations suggest that XH2+ (X = Si, Ge)

CollectionsANU Research Publications
Date published: 2000
Type: Journal article
URI: http://hdl.handle.net/1885/89042
Source: Angewandte Chemie International Edition
DOI: 10.1002/(SICI)1521-3773(20000417)39:8<1445::AID-ANIE1445>3.0.CO;2-Y

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