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Kinetics and Mechanism for Reversible Chloride Transfer between Mercury(II) and Square-Planar Platinum(II) Chloro Ammine, Aqua, and Sulfoxide Complexes. Stabilities, Spectra, and Reactivities of Transient Metal-Metal Bonded Platinum-Mercury Adducts

Groning, Osten; Sargeson, Alan; Deeth, R; Elding, Lars


The Hg2+(aq-) and HgCl+(aq-)assisted aquations of [PtCl4]2- (1), [PtCl3(H2O)]- (2), cis-[PtCl2(H2O)2] (3), trans-[PtCl2(H2O)2] (4), [PtCl(H2O)3]+ (5), [PtCl3Me2SO]- (6), trans-[PtCl2(H2O)Me2SO] (7), cis-[PtCl(H2O)2Me2-SO]+ (8), trans-[PtCl(H2O)2Me2SO]+ (9), trans-[PtCl2(NH3)2] (10), and cis-[PtCl2(NH3)2] (11) have been studied at 25.0 °C in a 1.00 M HClO4 medium buffered with chloride, using stopped-flow and conventional spectrophotometry. Saturation kinetics and instantaneous, large UV/vis...[Show more]

CollectionsANU Research Publications
Date published: 2000
Type: Journal article
Source: Inorganic Chemistry
DOI: 10.1021/ic000320j


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