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Raman-spectral depolarisation ratios of ions in concentrated aqueous solution. The next-to-negligible effect of highly asymmetric ion surroundings on the symmetry properties of polarisability changes during vibrations of symmetrc ions. Ammonium sulphate and teramethylammonium bromide.

Spinner, Ernest

Description

Depolarisation ratios ρ have been measured for the Raman spectra of solutions of composition (NH4)2 SO4 · 11H2O and (CH3)4NBr · 29D2O. Even though the former's vibration spectrum shows clear evidence of lowered ion symmetries (presence of ν1 of SO42-

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
URI: http://hdl.handle.net/1885/88530
Source: Spectrochimica Acta: part A
DOI: 10.1016/S1386-1425(02)00293-7

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