Strategic use of amino acid N -substituents to limit α-carbon-centered radical formation and consequent loss of stereochemical integrity
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Croft, Anna; Easton, Christopher; Kociuba, Katherine; Radom, Leo
Description
Ab initio calculations have been used to investigate the effect of N-substituents on the stability of α-carbon-centered amino acid radicals. Optimized structures of glycine derivatives and related substituted methanes, and the corresponding radicals, wer
Collections | ANU Research Publications |
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Date published: | 2003 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/88399 |
Source: | Tetrahedron: Asymmetry |
DOI: | 10.1016/S0957-4166(03)00542-1 |
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