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Strategic use of amino acid N -substituents to limit α-carbon-centered radical formation and consequent loss of stereochemical integrity

Croft, Anna; Easton, Christopher; Kociuba, Katherine; Radom, Leo


Ab initio calculations have been used to investigate the effect of N-substituents on the stability of α-carbon-centered amino acid radicals. Optimized structures of glycine derivatives and related substituted methanes, and the corresponding radicals, wer

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
Source: Tetrahedron: Asymmetry
DOI: 10.1016/S0957-4166(03)00542-1


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