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Conversion of Gibberellic Acid into the B-Ring seco -Kaurenoid, Longirabdolactone

Adamson, George; Mander, Lewis


The base-catalyzed rearrangement of an α-hydroxy aldehyde derived from the gibberellin GA15 results in ring-expansion of the five-membered B-ring of the gibberellin molecule and transformation into an ent-kaurene derivative. Further manipulation affords

CollectionsANU Research Publications
Date published: 2003
Type: Journal article
Source: Australian Journal of Chemistry
DOI: 10.1071/CH03048


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