Conversion of Gibberellic Acid into the B-Ring seco -Kaurenoid, Longirabdolactone
The base-catalyzed rearrangement of an α-hydroxy aldehyde derived from the gibberellin GA15 results in ring-expansion of the five-membered B-ring of the gibberellin molecule and transformation into an ent-kaurene derivative. Further manipulation affords
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|Source:||Australian Journal of Chemistry|
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